Analytical and spectroscopic study of copper compounds with diamine donor new ligands
Keywords:
Schiff base complex, copper complexes, Azo ligand dyeAbstract
Naphthylenediamine dihydrochloride and 4-nitroaniline were utilized to make N-(1-Naphthylethylenediamine dihydrochloride) naphthalen-1-amine, an azo ligand, in this case. It was possible to synthesize four new Cu (II) complexes by using four different compounds, including the primary ligand azo, as well as the secondarily used sodium-pyriphosphate-oxalic- and malonic-acid-based secondary ligands. Spectroscopy (UV-Vis, FTIR, mass, 1H-NMR spectra; atomic absorption; elemental analysis); magnetics; and molar conductivity were all used to thoroughly evaluate the produced substances. They found that all of the complexes were non-electrolytic and that all of the bivalent ligands were in coordination with copper (II) using infrared spectrum and molar conductivity data. Tetrahedral geometry of the complexes was discovered through the use of magnetic susceptibility measurements, mass spectrometric data, elemental analysis, H-NMR data, and ultraviolet visible spectra.
Downloads
References
Al-Adely, K. J. Synthesis and Spectrophotometric Studies of Some Transition Metal Complexes with New Azo Dye 2-[2-(6-Methoxy benzothiazolyl) azo]-4-Nitro Phenol. Asian Journal of Chemistry, Vol.24(12), 5597. (2012).
Aljamali and Alfatlawi,2015. Synthesis of Sulfur Heterocyclic Compounds and Study of Expected Biological Activity. Research J. Pharm. and Tech. 8(9): Sept 2015.
Amin A.S., Zaafarany I.A.(2015). Spectrophotometric determination of iridium after complexation and membrane filtration, Analytical Chemistry Research. Volume 3, P 77-81.
Azahari, S. J., Rhman, M. H. A., & Mostafa, M. M. Spectroscopic, analytical and DFT calculation studies of two novel Al3+ complexes derived from 2, 4,6-tri-(2-pyridyl)-1, 3, 5-triazine (TPTZ). Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, Vol.132, 165-173. (2014).
Bayrak H.E.,Bulut V.N., Tufekci M.,Bayrak H.,Duran C., Soylak M.(2016).Determination of Au(III) and Pd(II) ions by flame atomic absorption spectrometry in some environmental samples after solid phase extraction, Toxicological & Environmental Chemistry,V 99,P 590-600.
Bhatt V.(2016). Chapter 1 –Basic Coordination Chemistry, Essentials of Coordination Chemistry, P1-35.
Dhongde R, De B.S & Wasewar L. Experimental Study on Reactive Extraction
Djuraev, A. M., Alpisbaev, K. S., & Tapilov, E. A. (2021). The choice of surgical tactics for the treatment of children with destructive pathological dislocation of the hip after hematogenous osteomyelitis. International Journal of Health & Medical Sciences, 5(1), 15-20. https://doi.org/10.21744/ijhms.v5n1.1813
Hadi Kargar; Fariba Aghaei-Meybodi;Mohammad Reza Elahifard;Muhammad Nawaz Tahir;Muhammad Ashfaq;Khurram Shahzad Munawar; (2021). Some new Cu(II) complexes containing O,N-donor Schiff base ligands derived from 4-aminoantipyrine: synthesis, characterization, crystal structure and substitution effect on antimicrobial activity . Journal of Coordination Chemistry.
House J.E.(2013).Introduction to Coordination Chemistry, Inorganic Chemistry (Second Edition), P 553-590.
Inorganic Electronic Spectroscopy Lever AB 1968
Ioannou, Aristos (2016). Real Time Monitoring the Maillard Reaction Intermediates by HPLC- FTIR. Journal of Physical Chemistry & Biophysics, 6(2).
J. Chem. Eng,Vol 64,P 1072–1084.(2019).
Miller J.N. and Miller J.C.Statistics and Chemometrics for Analytical chemistry, 6th Ed; Prentice Hall, England.(2010).
Onda K. Diverse Photoinduced Dynamics in an Organic ChargeTransfer Complex Having Strong Electron–Phonon Interactions, Acc.Chem, V47, P3494–3503.(2014).
S. K. Kumar , P. S. Rao, L. Krishnaniah, B. Jayaraj and P. Chiranjeevi; Anal.sci; 20, (2004), 951.
Suryasa, I. W., Rodríguez-Gámez, M., & Koldoris, T. (2022). Post-pandemic health and its sustainability: Educational situation. International Journal of Health Sciences, 6(1), i-v. https://doi.org/10.53730/ijhs.v6n1.5949
Y. N. Vashisht Gopal and A.K.Kondapi ; J . Biosci, 26, (2001), 271
Published
How to Cite
Issue
Section
Copyright (c) 2022 International journal of health sciences
This work is licensed under a Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License.
Articles published in the International Journal of Health Sciences (IJHS) are available under Creative Commons Attribution Non-Commercial No Derivatives Licence (CC BY-NC-ND 4.0). Authors retain copyright in their work and grant IJHS right of first publication under CC BY-NC-ND 4.0. Users have the right to read, download, copy, distribute, print, search, or link to the full texts of articles in this journal, and to use them for any other lawful purpose.
Articles published in IJHS can be copied, communicated and shared in their published form for non-commercial purposes provided full attribution is given to the author and the journal. Authors are able to enter into separate, additional contractual arrangements for the non-exclusive distribution of the journal's published version of the work (e.g., post it to an institutional repository or publish it in a book), with an acknowledgment of its initial publication in this journal.
This copyright notice applies to articles published in IJHS volumes 4 onwards. Please read about the copyright notices for previous volumes under Journal History.
