Novel laboratory extraction method using magnetically micro bubble stream

Emad Kadhim Atiyah; Mustafa Abdulkadhim Hussein

doi:10.53730/ijhs.v6nS6.11972

Authors

Emad Kadhim Atiyah
mustafa.rabeea@uokufa.edu.iq
Chemistry Department, Faculty of Science, Kufa University, Iraq
Mustafa Abdulkadhim Hussein South Refineries Company / Maysan Refinery Department

Keywords:

novel laboratory, extraction method, magnetically micro, bubble stream

Abstract

Innovative, sensitive and accurate method for liquid-liquid extraction using bubble phenomenon. is presented in this work. A working system was designed, consisting of two basic parts: the pump air to generate the bubbles and the pump device, to pump or withdraw the organic layer from the liquid-liquid system key variables study was performed in the system containg Dithizone (0.001 M) in CHCl₃ solvent and aqueous copper (II) chloride (1000 ppm) solution to find out the extent of their impact on the extraction performance obtained in this way. The effect of copper concentration in the initial sample, shake time, size of bubbles flowrate were studied, fixing the optimal conditions: for a sample of (10 mL) aqueous solution of Cu (II) chloride, the optimum copper (II) concentration in the analyzed sample is (0.0001M) , the size of bubbles 2.6 L\min, the shaking time is (15 min), and the pump flowrate is ( 50sec/mL). In these optimum conditions, the extraction degree was (91.1 %). The results of the innovative bubbles extraction method were compared with previous studies, and found they were more efficient than the classical methods of extraction using funnel separation and multiple extraction.

Downloads

Download data is not yet available.

References

A. Baba, K. I. Ayinla, F. A. Adekola, M. K. Ghosh, P. C. Rout, and A. I. Ambo, “Extraction and purification of copper from a Nigerian chalcopyrite ore leach liquor by dithizone in kerosene,” Solvent Extr. Res. Dev. Japan, vol. 22, no. 2, pp. 135–146, 2015.

Alafara Abdullahi Baba,Ibrahim Ayinla,Malay Kumar Ghosh & Folahan Adekola"Extraction and Purification of Copper from a Nigerian Chalcopyrite Ore Leach Liquor by Dithizone in Kerosene", Japan magazine ,vol. 22, No. 2, May 2015.”

N. Mulligan, N. Davarpanah, M. Fukue, and T. Inoue, “Filtration of contaminated suspended solids for the treatment of surface water,” Chemosphere, vol. 74, no. 6, pp. 779–786, 2009.

Douglas A. Skoog, Donald M. West, F. James Holler, Stanley R. Crouch , ’ ’Fundamentals of Analytical Chemistry ’ ’, 9th Ed ,Crouch Publisher publishing house , 2013.”

E. N. Ali, S. A. Muyibi, H. M. Salleh, M. R. M. Salleh, and M. Alam, ‘Moringa oleifera seeds as natural coagulant for water treatment,’ in Thirteenth international Egyptian water technology conference, 2009, pp. 163–168.”

G. Z. Kyzas, A. C. Mitropoulos, and K. A. Matis, “From microbubbles to nanobubbles: effect on flotation,” Processes, vol. 9, no. 8, p. 1287, 2021.

J.-A. Hong, J.-S. Lee, and Y.-D. Jun, “Characterization of Extracted Dissolved Gas from Water,” J. Human-centric Sci. Technol. Innov, vol. 1, no. 2, pp. 23–30, 2021.

K. J. Laidler . ,"Chemical kinetics", 3th.Ed ,Harper publishing house ,New York ,1987.”

K. J. Laidler ‘Chemical kinetics’ Harper publishing house ,3th.Ed ,New York (1987) 111-113.”

K. Pongmala et al., “Modelling total suspended solids, E. coli and carbamazepine, a tracer of wastewater contamination from combined sewer overflows,” J. Hydrol., vol. 531, pp. 830–839, 2015.

Kalavathy, M.H. and Miranda, L.R. (2010). Moringa oleifera—A Solid Phase Extractant for The Removal of Copper, Nickel and Zinc from Aqueous Solutions. Chemical Engineering Journal, 158, 188-199.”

Obuseng, V., Nareetsile, F. and Kwaambwa, H.M. (2012). A Study of The Removal of Heavy Metals from Aqueous Solutions by Moringa oleifera Seeds and Amine-Based Ligand 1, 4-bis [N, N-bis (2-picoyl) amino] butane. Analytica Chimica Acta, 730, 87– 92.”

P. L. Hibbard, “Estimation of Copper, Zinc, and Cobalt (with Nickel) in Soil Extracts Dithizone Methods Particularly Adapted to Examination of Soils,” Ind. Eng. Chem. Anal. Ed., vol. 10, no. 10, pp. 615–618, 1938.

Parmin, P., Suarayasa, K., & Wandira, B. A. (2020). Relationship between quality of service with patient loyality at general polyclinic of kamonji public health center. International Journal of Health & Medical Sciences, 3(1), 86-91. https://doi.org/10.31295/ijhms.v3n1.157

Paula, H.M., Oliveira Ilha, M.S. and Andrade, L.S. (2014). Concrete Plant Wastewater Treatment Process by Coagulation Combining Aluminum Sulfate and Moringa oleifera Powder. Journal of Cleaner Production, 76, 125-130.”

Prevenslik T., Proc. of Conf. ‘Topical Problems of Fluid Mechnics’, p. 113, Prague 2014.”

S. Armenta, S. Garrigues, and M. de la Guardia, “The role of green extraction techniques in Green Analytical Chemistry,” TrAC - Trends Anal. Chem., vol. 71, pp. 2–8, 2015, doi: 10.1016/j.trac.2014.12.011.

S. Mishra et al., “Heavy metal contamination: an alarming threat to environment and human health,” in Environmental biotechnology: For sustainable future, Springer, 2019, pp. 103–125.

Shannon, M. A.; Bohn, P. W.; Elimelech, M.; Georgiadis, J. G.; Marinas, B. J.; Mayes, A. M. Science and technology for water purification in the coming decades. Nature 2008, 452, 301−310.”

Sholl, D. S.; Lively, R. P. Seven chemical separations to change the world. Nature 2016, 532, 435−437.”

Suryasa, I. W., Rodríguez-Gámez, M., & Koldoris, T. (2021). The COVID-19 pandemic. International Journal of Health Sciences, 5(2), vi-ix. https://doi.org/10.53730/ijhs.v5n2.2937

V. O. N. Njoku, C. Arinze, I. F. Chizoruo, and E. N. Blessing, “A Review: Effects of air, water and land dumpsite on human health and analytical methods for determination of pollutants,” Anal. Methods Environ. Chem. J., vol. 4, no. 03, pp. 80–106, 2021.