Synthesis and characterization of pure and Au doped Fe3O4 using co-precipitation method
Keywords:
synthesis, characterization pure, Au doped Fe3O4, co-precipitation methodAbstract
In this research, a sonochemical activation-assisted biosynthesis of Au/Fe3O4 nanoparticles is proposed. The proposed synthesis methodology incorporates the use of Piper auritum (an endemic plant) as reducing agent and in a complementary way, an ultrasonication process to promote the synthesis of the plasmonic/magnetic nanoparticles (Au/Fe3O4). The synergic effect of the green and sonochemical synthesis favors the well-dispersion of precursor salts and the subsequent growth of the Au/Fe3O4 nanoparticles. The hybrid green/sonochemical process generates an economical, ecological and simplified alternative to synthesizing Au/Fe3O4 nanoparticles whit enhanced catalytic activity, pronounced magnetic properties. The morphological, chemical and structural characterization was carried out by high- resolution Scanning electron microscopy (HR-SEM), Energy Dispersive X-Ray Spectroscopy (EDS) and X-Ray diffraction (XRD), respectively. Ultraviolet–visible (UV–vis) and X-ray photoelectron (XPS) spectroscopy confirm the Au/Fe3O4 nanoparticles obtention. Finally, the catalytic activity was evaluated by sonocatalytic degradation of methyl orange (MO). In this stage, it was possible to achieve a removal percentage of 91.2% at 15 min of the sonocatalytic process (160 W/42 kHz). The initial concentration of the MO was 20 mg L 1, and the Fe3O4-Au dosage was 0.075 gL 1.
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Aguilar-Urquizo, E., Itza-Ortiz, M. F., Sangines-Garcia, J. R., Pineiro-Vázquez, A. T., Reyes-Ramirez, A., & Pinacho-Santana, B. (2020). Phytobiotic activity of piper auritum and ocimum basilicum on avian e. Coli. Brazilian Journal of Poultry Science, 22.
Bindes, M. M. M., Reis, M. H. M., Cardoso, V. L., & Boffito, D. C. (2019). Ultrasound-assisted extraction of bioactive compounds from green tea leaves and clarification with natural coagulants (chitosan and Moringa oleífera seeds). Ultrasonics sonochemistry, 51,pp. 111-119.
Conde-Hernández, L. A., & Guerrero-Beltrán, J. Á. (2014). Total phenolics and antioxidant activity of Piper auritum and Porophyllum ruderale. Food chemistry, 142,pp. 455-460.
Crase, S. J., Hockaday, C., & McCarville, P. C. (2007). Brief report: Perceptions of positive and negative support: Do they differ for pregnant/parenting adolescents and nonpregnant, nonparenting adolescents?. Journal of Adolescence, 30(3),pp. 505-512.
de Jesús Ruíz-Baltazar, Á. (2020). Green synthesis assisted by sonochemical activation of Fe3O4-Ag nano-alloys: Structural characterization and studies of sorption of cationic dyes. Inorganic Chemistry Communications, 120,p. 108148.
de Jesus Ruiz-Baltazar, A. (2020). Kinetic adsorption models of silver nanoparticles biosynthesized by Cnicus Benedictus: Study of the photocatalytic degradation of methylene blue and antibacterial activity. Inorganic Chemistry Communications, 120,p. 108158.
de Jesús Ruíz-Baltazar, Á., Reyes-López, S. Y., de Lourdes Mondragón-Sánchez, M., Estevez, M., Hernández-Martinez, A. R., & Pérez, R. (2018). Biosynthesis of Ag nanoparticles using Cynara cardunculus leaf extract: evaluation of their antibacterial and electrochemical activity. Results in Physics, 11,pp. 1142-1149.
Eghbali, P., Hassani, A., Sündü, B., & Metin, Ö. (2019). Strontium titanate nanocubes assembled on mesoporous graphitic carbon nitride (SrTiO3/mpg-C3N4): Preparation, characterization and catalytic performance. Journal of Molecular Liquids, 290,p. 111208.
Elshikh, M. S., Chen, T. W., Mani, G., Chen, S. M., Huang, P. J., Ali, M. A., ... & Al-Mohaimeed, A. M. (2021). Green sonochemical synthesis and fabrication of cubic MnFe2O4 electrocatalyst decorated carbon nitride nanohybrid for neurotransmitter detection in serum samples. Ultrasonics sonochemistry, 70, p.105305.
Ghanbari, F., Zirrahi, F., Lin, K. Y. A., Kakavandi, B., & Hassani, A. (2020). Enhanced electro-peroxone using ultrasound irradiation for the degradation of organic compounds: A comparative study. Journal of Environmental Chemical Engineering, 8(5), p.104167.
Jain, B., Hashmi, A., Sanwaria, S., Singh, A. K., Susan, M. A. B. H., & Carabineiro, S. A. (2020). Catalytic properties of graphene oxide synthesized by a “Green” process for efficient abatement of Auramine-O cationic dye. Analytical Chemistry Letters, 10(1),pp. 21-32.
Khataee, A., Rad, T. S., Nikzat, S., Hassani, A., Aslan, M. H., Kobya, M., & Demirbaş, E. (2019). Fabrication of NiFe layered double hydroxide/reduced graphene oxide (NiFe-LDH/rGO) nanocomposite with enhanced sonophotocatalytic activity for the degradation of moxifloxacin. Chemical Engineering Journal, 375,p. 122102.
Khodadadi, B., Bordbar, M., & Nasrollahzadeh, M. (2017). Achillea millefolium L. extract mediated green synthesis of waste peach kernel shell supported silver nanoparticles: application of the nanoparticles for catalytic reduction of a variety of dyes in water. Journal of colloid and interface science, 493,pp. 85-93.
Lin, F. H., & Doong, R. A. (2017). Catalytic nanoreactors of Au@ Fe3O4 yolk–shell nanostructures with various au sizes for efficient nitroarene reduction. The Journal of Physical Chemistry C, 121(14),pp. 7844-7853.
Lumbaque, E. C., Tiburtius, E. R. L., Barreto-Rodrigues, M., & Sirtori, C. (2019). Current trends in the use of zero-valent iron (Fe0) for degradation of pharmaceuticals present in different water matrices. Trends in Environmental Analytical Chemistry, 24, e00069.
Pandey, P., Goel, V. K., Mishra, M., & Pandey, S. (2022). Comparative analysis of conventional X-ray chest Vs. NCCT chest in patients of blunt trauma chest: An observational study. International Journal of Health Sciences, 6(S5), 10179–10187. https://doi.org/10.53730/ijhs.v6nS5.10763
Qasim, S., Zafar, A., Saif, M. S., Ali, Z., Nazar, M., Waqas, M., ... & Hasan, M. (2020). Green synthesis of iron oxide nanorods using Withania coagulans extract improved photocatalytic degradation and antimicrobial activity. Journal of Photochemistry and Photobiology B: Biology, 204,p. 111784.
Roy, F., Taouil, A. E., Lallemand, F., Heintz, O., Moutarlier, V., & Hihn, J. Y. (2018). Alkanethiol self-assembling on gold: Influence of high frequency ultrasound on adsorption kinetics and electrochemical blocking. Ultrasonics sonochemistry, 40,pp. 9-16.
Samuel, M. S., Jose, S., Selvarajan, E., Mathimani, T., & Pugazhendhi, A. (2020). Biosynthesized silver nanoparticles using Bacillus amyloliquefaciens; Application for cytotoxicity effect on A549 cell line and photocatalytic degradation of p-nitrophenol. Journal of Photochemistry and Photobiology B: Biology, 202,p. 111642.
Suandayani, N. K. T. ., Sutapa, G. N. ., & Kasmawan, I. G. A. . (2020). Quality control of X-rays with collimator and the beam alignment test tool. International Journal of Physical Sciences and Engineering, 4(3), 7–15. https://doi.org/10.29332/ijpse.v4n3.468
Thamilselvan, A., Manivel, P., Rajagopal, V., Nesakumar, N., & Suryanarayanan, V. (2019). Improved electrocatalytic activity of Au@ Fe3O4 magnetic nanoparticles for sensitive dopamine detection. Colloids and Surfaces B: Biointerfaces, 180,pp. 1-8.
Thari, F. Z., Tachallait, H., El Alaoui, N. E., Talha, A., Arshad, S., Álvarez, E., ... & Bougrin, K. (2020). Ultrasound-assisted one-pot green synthesis of new N-substituted-5-arylidene-thiazolidine-2, 4-dione-isoxazoline derivatives using NaCl/Oxone/Na3PO4 in aqueous media. Ultrasonics sonochemistry, 68,p. 105222.
Vickers, N. J. (2017). Animal communication: when i’m calling you, will you answer too?. Current biology, 27(14), pp.713-715.
Vickers, N. J. (2017). Animal communication: when i’m calling you, will you answer too?. Current biology, 27(14),pp. 713-715.
Vijilvani, C., Bindhu, M. R., Frincy, F. C., AlSalhi, M. S., Sabitha, S., Saravanakumar, K., ... & Atif, M. (2020). Antimicrobial and catalytic activities of biosynthesized gold, silver and palladium nanoparticles from Solanum nigurum leaves. Journal of Photochemistry and Photobiology B: Biology, 202,p. 111713.
Widana, I.K., Sumetri, N.W., Sutapa, I.K., Suryasa, W. (2021). Anthropometric measures for better cardiovascular and musculoskeletal health. Computer Applications in Engineering Education, 29(3), 550–561. https://doi.org/10.1002/cae.22202
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