A novel ion- selective electrode sensor based on crafted polymer sugar thia crown ether for the determination of Cadmium (II)

Fadhil Faez Sead; Hussein Jasim Mohammed; Ahmed Ibrahim Hamzah; Ghadeer Sabah Bustani

doi:10.53730/ijhs.v6nS2.5150

Authors

Fadhil Faez Sead
fadhil.faiz@iunajaf.edu.iq
Department of Chemistry, Faculty of Dentistry, The Islamic University, Najaf, Iraq
Hussein Jasim Mohammed Department of Chemistry, Faculty of Science, University of Kufa , Iraq
Ahmed Ibrahim Hamzah Department of Medical Laboratory Technique, Altoosi University College, Najaf Iraq
Ghadeer Sabah Bustani Department of Chemistry, Faculty of Dentistry, The Islamic University, Najaf, Iraq | Department of Medical Laboratory Technique, Altoosi University College, Najaf Iraq

Keywords:

cadmium, crown ether, ion-selective electrode, potentiometric sensor, thia polymeric

Abstract

A Cadmium (II) ion-selective electrode (ISE) based on Thia polymeric crown ether (SPCE-Cd²⁺) as a membrane carrier in a PVC matrix was successfully built for the determination of Cd²⁺ ions. Using Dimethyl phthalate (DMP) plasticizer, the electrode showed a Nernstian liner response spanning the range of 1*10^-1 to 1*10^-7 M with a slope of (28) ±2 mV per decade charge and a detection limit of 1*10^-9 M. The sensor has a 10-second response time. The cadmium ion-selective electrode is highly precise in its selectivity for Cd²⁺ over other cations. Some alkali and transition metal ions have selectivity coefficients in the range of 1 * 10^-7 to 1 * 10^-1. It worked well as an indicator electrode in the potentiometric measurement of the cadmium ion.

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