Corrosion inhibitor of carbon steel in 3.5%NaCl solution with Schiff base compounds
Keywords:
Polarization, inhibition, Carbon steel, Schiff base, Corrosion potentialAbstract
In this work, synthesized N4,N4`-bis(2, 3, 4 nitro benzylidene) biphenyi-4-4`-diamine(B1-B3) , was tested as an inhibitors in controlling the corrosion of carbon steel in NaCl 3.5% solution by using open circuit potential (OCP),at four different temperatures (293, 303, 313 and 323 K). Furthermore, the surface morphology was investigated using the Atomic force microscopy (AFM). The effect of using different Schiff bases and temperature was also investigated. Schiff bases was synthesized and characterized via using. Fourier Transform Infrared Spectroscopy (FT-IR)and Atomic Force Microscope (AFM) characterized . The experimental results shown that Schiff bases can consider as an excellent corrosion inhibitors for carbon steel in NaCl 3.5% solution, by presence of Schiff bases the corrosion of carbon steel was significantly suppressed. The inhibition efficiency is decreased with the increases of temperature. Kinetic and thermodynamic activation parameters (Ea, A, ΔH*, ΔS* and ΔG*) were calculated.
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P.R., Handbook of corrosion Engineering, the McGraw-Hill Companies, Inc,2000:p.833-868.
P.Bertrand, A. Jonas, A. Laschewsky, and R. Legras, Ultrathin polymer coatings by complexation of polyelectrolytes at interfaces: suitable materials, structure and properties. Macromolecular Rapid Communications, 2000. 21(7): p. 319-348.
P. T.Hammond, Recent explorations in electrostatic multilayer thin film assembly. Current Opinion in Colloid & Interface Science, 1999. 4(6): p. 430-442.
Hammond, Form and function in multilayer assembly: new applications at the nanoscale. Advanced Materials, 2004. 16(15): p. 1271-1293.
J. Kumar, A. Rai, and V. Raj, "A comprehensive review on the pharmacological activity of schiff base containing derivatives", Org Med Chem J, vol. 1, pp. 555-64, 2017.
A. Jarrahpour, M. Zarei, "Synthesis of 2-({[4-(4-{[(E)-1-(2-hydroxy-3-methoxyphenyl) methylidene] amino} phenoxy) phenyl] imino} methyl)-6-methoxy phenol", Molbank, vol. 2004, p. 352, 2004.
C. M. Da Silva, D. L. da Silva, L. V. Modolo, R. B. Alves, M. A. de Resende, C. V. Martins, et al., "Schiff bases: A short review of their antimicrobial activities", Journal of Advanced research, vol. 2, pp. 1-8, 2011.
V. Saxena, "Schiff’s Bases as an Antimicrobial Agent: A Short Review", International journal of basic and applied research, vol.9, pp. 513-522, 2019.
O. A. Ali, S. M. El-Medani, M. R. A. Serea, and A. S. Sayed, "Unsymmetrical Schiff base (ON) ligand on complexation with some transition metal ions: Synthesis, spectral characterization, antibacterial, fluorescence and thermal studies", Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, vol. 136, pp. 651-660, 2015.
Obot, I., and Obi-Egbedi, N., 2,3-Diphenyl benzoquinoxaline: a new corrosion inhibitor for mild steel in sulphuric acid, Corros. Sci., 52(1): 282-285, (2010).
Umoren, S., Obot, I., Ebenso, E., and Obi-Egbedi, N., Synergistic inhibition between naturally occurring exudate gum and halide ions on the corrosion of mild steel in acidic medium, Int. J. Electrochem. Sci., 3: 1029-1043, (2008).
Bockris, J., Genshaw, M., Brusic, V., and Wroblowa, H., The mechanism of the passivation of iron and coulometric investigation, Electrochim. Acta., 16: 1859-1894, (1971).
S. M. Al-Majidi, U. H. Al-Jeilawi, and A. Khulood, "Synthesis and characterization of some 2-sulphanyl benzimidazole derivatives and study of effect as corrosion inhibitors for carbon steel in sulfuric acid solution", Iraqi Journal of Science, vol. 54, pp. 789-802, 2013.
Naeimi, H., and Rabiei,K., Montmorillonite as a heterogeneous catalyst in the efficient, mild and one pot synthesis of schiff bases under solvent-free conditions, J. Chin. Chem. Soc., 58(6): 1-5,(2011).
Khulood, A.S. Khalil, S.K. and Muna, I.K. 2018. Preparation of poly (N-imidazolylmaleamic acid) /nanomaterial coating films on stainless steel by electrochemicalpolymerization to study the anticorrosion and antibacterial action . Journal of Pharmacy and Biological Sciences, 13: 30-36.
Silverstein R.M., Webster, F.X. and Kiemle, D.J. 1963.Spectrometric Identification of Organic Compounds, 7th ed., John Wiley & Sons, Westford, US.
Shirner, R., Fuson, R., Cartin, D. and Mrril, T. 1980. The systematic identification of organic compound, 8th ed., John Wiley & Sons, Ne. 30. Koj, N. 1962.Infrared absorption spectroscopy, 1st ed., Nankodo Cmpany Limited, Tokyo.
Devi, B., and Rajendran, S., Influence of garlic extract on the inhibition efficiency of tri sodium citrate, Int. J. Chem. Sci.& Techno., 1: 79-87, (2011).
E.Heitz, and W. Schwenk, Theoretical basis for the determination of corrosion rates from polarization resistance: prepared for the european federation of corrosion working partyon Physiocochemical testing method of corrosion fundamentals and application, British Corrosion J., 1976.11(2), p: 74-77.
N.A.Hikmat and S.A.Mahmood. Comparispon study on corrosion protectiveness of nanostructured electropolymerized polyaniline derivitives. 2015. M.Sc. Thesis. College of science, University of Baghdad.
M. Aliofkhazraei, Developments in Corrosion Protection, Chapter 16, Corrosion Inhibitors-Principles, Mechanisms and Applications, C. G. Dariva and A. F. Galio, Publisher: InTech, 2014. P. 367.
O. Kasso, M. Galai, R. A. Ballakhmima, N. Dkhireche, A. Rochdi M. Ebn Touhami, R. Touir and A. Zarrouk, Comparative Study of Low Carbon Steel Corrosion Inhibition in 200 ppm NaCl by Amino Acid Compounds, J. Mater. Environ. Sci., 2015. 6 (4) :P.9021199.
S. A. Kumar, A. Sankar, S. R. Kumar, Vitamin B-12 Solution as Corrosion Inhibitor for Mild Steel in Acid Medium, IJCES, 2013.3(1): P.57-61.
A. M. Al-sammarraie and R.A.Shaker. Corrosion protection enhancement of; zn, cu, al, carbon steel and stainless steel 316 artificial seawater by coating with nanomaterials. 2014. M.Sc. Thesis. College of science, University of Baghdad.
M. G. Fontana, Corrosion Engineering. . 3rd ed. McGraw-Hill. 1987. Vol. 3. New York.
B. Joseph, S. John, A. Joseph and B. Narayana, Imidazolidine-2thione as Corrosion Inhibitor for Mild Steel in Hydrochloric Acid, Indian Journal of Chemical Technology,2010, 17,p. 366-374.
M. Mobin, S. Zehra and M. Parveen, L-Cysteine as Corrosion Inhibitor for Mild Steel in 1M HCl and Synergistic Effect of Anionic, Cationic and Non-Ionic Surfactants, Journal of Molecular Liquids, 2016, 216.p. 598–607. 172
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