Removal of methyl orange dye using(ZnO/MWCNTs) nanomaterial

https://doi.org/10.53730/ijhs.v6nS3.9371

Authors

  • Amir Fahdil Dawood Al-Niaimi Depatment of Chemistry, College of Science, University of Diyala, Diyala, Iraq
  • Esraa Ibraheim Mahmood Depatment of Chemistry, College of Science, University of Diyala, Diyala, Iraq

Keywords:

methyl orange, nanomaterial, exothermic

Abstract

The (ZnO/MWCNTs) Nano composite had a composition of (0.8/0.018MWCNTs) (w/w). Batch adsorption method was used to remove Methyl orang dye from its aqueous solution. The structural characteristics of  (ZnO/MWCNTs) were investigated (FTIR, XRD, BET,EDX,FE-SEM). The (ZnO) was discovered to have a 22 nm average particle size with surface area( 27.71m².g¯¹) . The (ZnO/MWCNTs ) was discovered to have a surface area(38.85m².g¯¹.). Adsorption equilibrium data was fitted with , Temkin equations to describe the isotherms, more than Freundlich,and Langmuir and Dubinin-Radushkevich isotherms. Thermodynamic studies showed  that the adsorption was exothermic and spontaneous and pysisorption nature of adsorption .The pseudo-first and second order models were used to fit the kinetic data, adsorption process flow the pseudo-second-order adsorption.

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References

AL-Niaimi, A. F. D., Atiya, G. I., & Abdulateef, D. A. (2018). Thermodynamics and kinetic study of Eosin dye adsorption on CuO nanoparticles. International Journal of Research in Pharmacy and Chemistry, 8(2), 281–293. www.ijrpc.com

Fahdil A, AL-Niaimi D, O. A. (2018). Adsorption of Orange G Dye from Aqueous Solutions Using Magnesium Oxide Nanoparticles. Journal of Biochemical Technology, 9(3), 31-38.

Dawood, A., Adris, G., & Ahmed, D. (2019). Thermodynamic and Kinetic Study of the Eosin Dye Removal from Aqueous Solution by ZnO Nanoparticles. Diyala Journal For Pure Science, 15(1), 55–75.

Crini, G. (2006). Non-conventional low-cost adsorbents for dye removal: a review. Bioresource technology, 97(9), 1061-1085.

Iranmanesh, S., Harding, T., Abedi, J., Seyedeyn-Azad, F., & Layzell, D. B. (2014). Adsorption of naphthenic acids on high surface area activated carbons. Journal of Environmental Science and Health, Part A, 49(8), 913-922.

Huang, C. P., & Wu, M. H. (1977). The removal of chromium (VI) from dilute aqueous solution by activated carbon. Water Research, 11(8), 673-679.

Jiang, Z., Liu, Y., Sun, X., Tian, F., Sun, F., Liang, C., ... & Li, C. (2003). Activated carbons chemically modified by concentrated H2SO4 for the adsorption of the pollutants from wastewater and the dibenzothiophene from fuel oils. Langmuir, 19(3), 731-736.‏‏‏‏

Wang, S., Zhu, Z. H., Coomes, A., Haghseresht, F., & Lu, G. Q. (2005). The physical and surface chemical characteristics of activated carbons and the adsorption of methylene blue from wastewater. Journal of colloid and interface science, 284(2), 440-446.

Grover, D. P., Zhou, J. L., Frickers, P. E., & Readman, J. W. (2011). Improved removal of estrogenic and pharmaceutical compounds in sewage effluent by full scale granular activated carbon: Impact on receiving river water. Journal of Hazardous Materials, 185(2-3), 1005-1011.

Demirbas, A. (2009). Agricultural based activated carbons for the removal of dyes from aqueous solutions: a review. Journal of hazardous materials, 167(1-3), 1-9.

Al-niaimi, A. F. D., & Kamel, R. L. (2020). Adsorption and Optical Color Decomposition of Congo Red Blue Solution Using Graphene Oxide / MnO 2 Nano Composite. 11, 74–84.

Sprynskyy, M., Szczyglewska, P., Wojtczak, I., Nowak, I., Witkowski, A., Buszewski, B., & Feliczak-Guzik, A. (2021). Diatom Biosilica Doped with Palladium (II) Chloride Nanoparticles as New Efficient Photocatalysts for Methyl Orange Degradation. International journal of molecular sciences, 22(13), 6734.

Ali, Z. R., & Dawood AL-Niaimi, A. F. (2022). A Structural and Electrical characterizations of new synthesized PVA/PoPDA-rGO-ZnO Nano composite. Egyptian Journal of Chemistry, 65(4), 1-2.‏‏‏‏‏‏‏

Mubarak, T. H., Hassan, K. H., & Abbas, Z. M. A. (2013). Using X-ray diffraction and scanning electron microscope to study zinc oxide nanoparticles prepared by wet chemical method. In Advanced Materials Research (Vol. 685, pp. 119-122). Trans Tech Publications Ltd.‏

Dawood, A. F., & Khalil, M. A. A. K. (2022). Removal of basic fuchsine dye using (TiO2/MWCNTs) nanomaterial. Materials Today: Proceedings, 49, 2888-2897.‏

Violet, C., Franco, P., Sacco, O., & Marco, I. De. (2019). Zinc Oxide Nanoparticles Obtained by Supercritical Antisolvent Precipitation for the Photocatalytic.

Rafique, S., Bashir, S., Akram, R., Kiyani, F. B., Raza, S., Hussain, M., & Fatima, S. K. (2022). Variation in the Performance of MWCNT/ZnO Hybrid Material with pH for Efficient Antibacterial Agent. BioMed Research International, 2022.

Fernandez-Garcia, M., Martinez-Arias, A., Hanson, J. C., and Rodriguez, J. A. (2004). Nanostructured oxides in chemistry: characterization and properties. Chemical Reviews, 104(9), 4063-4104.

Morsy, M., Helal, M., El-Okr, M., & Ibrahim, M. (2014). Preparation, purification and characterization of high purity multi-wall carbon nanotube. Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy, 132, 594–598.

Aravinda, L. S., Nagaraja, K. K., Nagaraja, H. S., Bhat, K. U., & Bhat, B. R. (2013). ZnO/carbon nanotube nanocomposite for high energy density supercapacitors. Electrochimica Acta, 95(2010), 119–124.

Feng, W., Chen, J., & Hou, C. yan. (2014). Growth and characterization of ZnO needles. Applied Nanoscience (Switzerland), 4(1), 15–18.

22- Saleh, T. A., Gondal, M. A., & Drmosh, Q. A. (2010). Preparation of a MWCNT/ZnO nanocomposite and its photocatalytic activity for the removal of cyanide from water using a laser. Nanotechnology, 21(49).

Franco, P., Sacco, O., De Marco, I., & Vaiano, V. (2019). Zinc oxide nanoparticles obtained by supercritical antisolvent precipitation for the photocatalytic degradation of crystal violet dye. Catalysts, 9(4), 346.‏

Sahebian, S., Zebarjad, S. M., & Lazzeri, A. (2015). A study on the dependence of structure of multi-walled carbon nanotubes on acid treatment. Journal of Nanostructure in Chemistry, 5(3), 287-293.‏

Sonune, A., & Ghate, R. (2004). Developments in wastewater treatment methods. Desalination, 167, 55-63.‏

Chen, Z. X., Jin, X. Y., Chen, Z., Megharaj, M., & Naidu, R. (2011). Removal of methyl orange from aqueous solution using bentonite-supported nanoscale zero-valent iron. Journal of Colloid and Interface Science, 363(2), 601–607.

Arora, C., Kumar, P., Soni, S., Mittal, J., Mittal, A., & Singh, B. (2020). Efficient removal of malachite green dye from aqueous solution using curcuma caesia based activated carbon. Desalination and Water Treatment, 195, 341–352.

Kumar, K. V. (2006). Comments on" Adsorption of acid dye onto organobentonite". Journal of hazardous materials, 137(1), 638-639.

Song, K., Xu, H., Xu, L., Xie, K., & Yang, Y. (2017). Cellulose nanocrystal-reinforced keratin bioadsorbent for effective removal of dyes from aqueous solution. Bioresource technology, 232, 254–262.

Fu, J., Chen, Z., Wang, M., Liu, S., Zhang, J., Zhang, J., ... & Xu, Q. (2015). Adsorption of methylene blue by a high-efficiency adsorbent (polydopamine microspheres): kinetics, isotherm, thermodynamics and mechanism analysis. Chemical Engineering Journal, 259, 53-61.‏

Wong, S., Tumari, H. H., Ngadi, N., Mohamed, N. B., Hassan, O., Mat, R., & Saidina Amin, N. A. (2019). Adsorption of anionic dyes on spent tea leaves modified with polyethyleneimine (PEI-STL). Journal of Cleaner Production, 206, 394–406.

Fahdil, A., Al-niaimi, D., & Muhi, F. H. (2019). Kinetic and Thermodynamic Study on the Removal of Congo Red from the Aqueous Solution Using Graphene Oxide / Magnesium Oxide Nanocomposite. 1–10.

Fahdil, Al-Niaimi, A. D., & Olaiwy, A. A. (2019). Removal Orange G dye from aqueous solutions using graphene oxide/magnesium oxide nano composite. International Journal of Research in Pharmacy and Chemistry, 9(1), 23-32.

Jaerger, S., Dos Santos, A., Fernandes, A. N., and Almeida, C. A. P. (2015). Removal of p-nitrophenol from aqueous solution using Brazilian peat: kinetic and thermodynamic studies. Water, Air, & Soil Pollution, 226(8), 236.‏

Olawale, S. A., & Okafor, C. C. (2020). Comparing the Different Methods Used in the Determination of Thermodynamic Parameters Using Adsorption of Pb ( II ) on to Chicken Feather as an Example. Jpurnal of Material Science an Reviews, 6(2), 1–11.

Errais, E., Duplay, J., Darragi, F., M’Rabet, I., Aubert, A., Huber, F., & Morvan, G. (2011). Efficient anionic dye adsorption on natural untreated clay: Kinetic study and thermodynamic parameters. Desalination, 275(1–3), 74–81.

Mahmoodi, N.M., Hayati, B., Bahrami, H. and Arami, M. (2011), "Dye Adsorption and Desorption Properties of Mentha pulegium in Single and Binary Systems". Journal of Applied Polymer Science, 122(3), pp: 1489-1499

Published

21-06-2022

How to Cite

Al-Niaimi, A. F. D., & Mahmood, E. I. (2022). Removal of methyl orange dye using(ZnO/MWCNTs) nanomaterial. International Journal of Health Sciences, 6(S3), 10138–10155. https://doi.org/10.53730/ijhs.v6nS3.9371

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Section

Peer Review Articles