Spectrophotometric determination of Co (II) in analytical sample using anew chromogenic reagent (PTMH)
Keywords:
optimal conditions, 1-phenyl-2-(thiophen-2-ylmethylene) hydrazine (PTMH), spectrophotometryAbstract
At the current work, the substrate phenyl hydrazine reacted with selected thiophene-2-carbaldehyde in absolute ethanol and a few drops of glacial acetic acid to give 1-phenyl-2-(thiophen-2-ylmethylene)hydrazine (PTMH) as a selective and sensitive reagent. It was synthesized and studied to determine cobalt spectroscopy in the following detail: at a pH value of 6.0, which greatly increased the selectivity, Co(II) reacted with (PTMH) to form a 1:2 complexes, with absorption peaks at 386 nm for cobalt. Under the optimal conditions, Beers law was obeyed over the ranges of (0.14ـــ5.8) mg/L. The apparent molar absorptivity and Sandell’s sensitivities were 7.1360×104 L.mol-1.cm-1, and 8.2585×10-4 µg.cm-2. The detection limits were found to be 0.0133 and the limit of quantification is 0.0466.
Downloads
References
Hanoon, H. D., Abd Al Hussain, H. A. & Abass, S. K. Synthesis and characterization of azetidin-2-one and 1, 3-oxazepine derivatives using Schiff bases derived from 1, 1’-biphenyl-4, 4’-diamine. in Journal of Physics: Conference Series vol. 2063 12010 (IOP Publishing, 2021).
Croitor, L. et al. Evolution from discrete mononuclear complexes to trinuclear linear cluster and 2D coordination polymers of Mn (II) with dihydrazone Schiff bases: Preparation, structure and thermal behavior. Polyhedron 206, 115329 (2021).
Kargar, H., Ardakani, A. A., Tahir, M. N., Ashfaq, M. & Munawar, K. S. Synthesis, spectral characterization, crystal structure determination and antimicrobial activity of Ni (II), Cu (II) and Zn (II) complexes with the Schiff base ligand derived from 3, 5-dibromosalicylaldehyde. J. Mol. Struct. 1229, 129842 (2021).
Kostova, I. & Saso, L. Advances in research of Schiff-base metal complexes as potent antioxidants. Curr. Med. Chem. 20, 4609–4632 (2013).
Şener, İ., Şener, N. & Gür, M. Synthesis, structural analysis, and absorption properties of disperse benzothiazol-derivative mono-azo dyes. J. Mol. Struct. 1174, 12–17 (2018).
Dalia, S. A. et al. A short review on chemistry of schiff base metal complexes and their catalytic application. Int. J. Chem. Stud. 6, 2859–2866 (2018).
Ardean, C. et al. Factors influencing the antibacterial activity of chitosan and chitosan modified by functionalization. Int. J. Mol. Sci. 22, 7449 (2021).
Altowyan, A. S., Ahmed, H. A., Gomha, S. M. & Mostafa, A. M. Optical and thermal investigations of new schiff base/ester systems in pure and mixed states. Polymers (Basel). 13, 1687 (2021).
Sun, J., Yang, Y., Wang, J. & Lu, B. Ammonia assisted regulation of nitrogen-type in carbonaceous support applied for oxygen reduction reaction. Appl. Surf. Sci. 558, 149958 (2021).
Kimura, I. et al. Maternal gut microbiota in pregnancy influences offspring metabolic phenotype in mice. Science (80-. ). 367, eaaw8429 (2020).
Swallow, A. J. Radiation Chemistry of Organic Compounds: International Series of Monographs on Radiation Effects in Materials. vol. 2 (Elsevier, 2016).
Zhang, W. et al. Hydrazone‐Linked Heptazine Polymeric Carbon Nitrides for Synergistic Visible‐Light‐Driven Catalysis. Chem. Eur. J. 26, 7358–7364 (2020).
Li, X., Zhang, D., Liu, Z., Xu, Y. & Wang, D. Synthesis, characterization of a ternary Cu (II) Schiff base complex with degradation activity of organophosphorus pesticides. Inorganica Chim. Acta 471, 280–289 (2018).
Coplen, T. B. & Shrestha, Y. Isotope-abundance variations and atomic weights of selected elements: 2016 (IUPAC Technical Report). Pure Appl. Chem. 88, 1203–1224 (2016).
M. A. C. M.Haniffa, Y. C.Ching, C. H.Chuah, K. Y.Ching, and N. S. L. Synergistic effect of (3-Aminopropyl) Trimethoxysilane treated ZnO and corundum nanoparticles under UV-irradiation on UV-cutoff and IR-absorption spectra of acrylic polyurethane based nanocomposite coating. Polym. Degrad. Stab. 159, 205–216 (2019).
Abu-Dief, A. M. et al. Synthesis and characterization of Fe (III), Pd (II) and Cu (II)-thiazole complexes; DFT, pharmacophore modeling, in-vitro assay and DNA binding studies. J. Mol. Liq. 326, 115277 (2021).
Srivastava, A. K., Yadav, P., Srivastava, K. & Prasad, J. Synthesis, characterization, biological and electrochemical investigation of copper (II) complexes containing 4-chloro-2-[2, 6-diisopropylphenylimino) methyl] phenol Schiff base ligand and aromatic diinines. Chem. Data Collect. 32, 100659 (2021).
A. G.Al-shahwany, and A. O. O. Synthesis and Study some new Schiff Bases Derived from Pyrazolo-Coumarin. Rafidain J. Sci. 30, 78–90 (2021).
Thota, A., Boga, K., Arukula, R., Narayan, R. & Rao, C. R. K. Dianiline conjugated Schiff base molecule: Electrical and electrochemical properties. Synth. Met. 247, 240–247 (2019).
Anand, T., Kumar, A. S. K. & Sahoo, S. K. A novel Schiff base derivative of pyridoxal for the optical sensing of Zn2+ and cysteine. Photochem. Photobiol. Sci. 17, 414–422 (2018).
Raafid, E., Al-Da’amy, M. A. & Kadhim, S. H. Determination and Identification of Nickel (II) Spectroscopy in Alloy Samples Using Chromogenic Reagent (HPEDN). in IOP Conference Series: Materials Science and Engineering vol. 871 12025 (IOP Publishing, 2020).
Haniffa, M. A. C. M., Ching, Y. C., Chuah, C. H., Ching, K. Y. & Liou, N.-S. Synergistic effect of (3-Aminopropyl) Trimethoxysilane treated ZnO and corundum nanoparticles under UV-irradiation on UV-cutoff and IR-absorption spectra of acrylic polyurethane based nanocomposite coating. Polym. Degrad. Stab. 159, 205–216 (2019).
M. H.Atiyah, and A. F. H. Spectrophotometric Determination of Micro Amount of Copper (II) Using a New of (Azo) Derivative, Study of Thermodynamic Functions and Their Analytical Application. Syst. Rev. Pharm. 11, 171–181 (2020).
Widana, I.K., Sumetri, N.W., Sutapa, I.K., Suryasa, W. (2021). Anthropometric measures for better cardiovascular and musculoskeletal health. Computer Applications in Engineering Education, 29(3), 550–561. https://doi.org/10.1002/cae.22202
Gandamayu, I. B. M., Antari, N. W. S., & Strisanti, I. A. S. (2022). The level of community compliance in implementing health protocols to prevent the spread of COVID-19. International Journal of Health & Medical Sciences, 5(2), 177-182. https://doi.org/10.21744/ijhms.v5n2.1897
Published
How to Cite
Issue
Section
Copyright (c) 2022 International journal of health sciences
This work is licensed under a Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License.
Articles published in the International Journal of Health Sciences (IJHS) are available under Creative Commons Attribution Non-Commercial No Derivatives Licence (CC BY-NC-ND 4.0). Authors retain copyright in their work and grant IJHS right of first publication under CC BY-NC-ND 4.0. Users have the right to read, download, copy, distribute, print, search, or link to the full texts of articles in this journal, and to use them for any other lawful purpose.
Articles published in IJHS can be copied, communicated and shared in their published form for non-commercial purposes provided full attribution is given to the author and the journal. Authors are able to enter into separate, additional contractual arrangements for the non-exclusive distribution of the journal's published version of the work (e.g., post it to an institutional repository or publish it in a book), with an acknowledgment of its initial publication in this journal.
This copyright notice applies to articles published in IJHS volumes 4 onwards. Please read about the copyright notices for previous volumes under Journal History.
