Synthesis and characterization of some new metals complexes of ((2-Chloro acetyl) carbamothioyl) glycine
Keywords:
glycine, chloro acetyl isothiocyanate, complexeAbstract
A new ligand ((2-Choroacetyl) carbamothioyl ) Glycine (CCG) is synthesized by reaction of (Chloro acetyl isothiocyanate) with Glycine (1:1). It is characterized by micro elemental analysis (C.H.N.S.), FT-IR, (UV-Vis) and 1H and 13CNMR spectra. Some metals ions complexes of this ligand were prepared and characterized byFT-IR,UV-Visible spectra ,conductivity measurements, magnetic susceptibility and atomic absorption. From results obtained, the following formula [M(CCG)2] where M2+ = Mn, Co, Ni, Cu, Zn, , Cd and Hg, the proposed molecular structure for these complexes as tetrahedral geometry, except copper complex is has square planer geometry.
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