Synthesis and characterization of arrested precipitation assembled Cu2Se thin films

https://doi.org/10.53730/ijhs.v6nS4.9605

Authors

  • S. M. Karape Assistant Professor Anandibai Raorane Arts, Commerce and Science College, Vaibhavwadi, Maharashtra, India
  • D. M. Sirsat Assistant Professor, Anandibai Raorane Arts, Commerce and Science College, Vaibhavwadi, Maharashtra, India
  • K. S. Pakhare Assistant Professor, Anandibai Raorane Arts, Commerce and Science College, Vaibhavwadi, Maharashtra, India
  • S. S. Jadhav Assistant Professor, Materials Research Laboratory, P. G. Department of Chemistry, Balwant College Vita, Maharashtra, India
  • S. T. Sankpal Assistant Professor, Dept. of Chemistry, Athalye Sapre Pitre College Devrukh, Ratnagiri, Maharashtra, India

Keywords:

arrested precipitation technique, thin films, copper selenide, optical properties

Abstract

Nanostructured thin films of copper selenide (Cu2Se) deposited by arrested precipitation technique (APT) with controlled release of ions at suitable pH=10.5. The deposited Cu2Se films were characterized for optical, structural, and morphological properties. Optical absorption study indicates that the band gap energy (2.26 eV) of material and shows visible radiation absorption. XRD shoe that APT is a favorable technique for the synthesis of pure nanocrystalline Cu2Se thin films with monoclinic crystal structure. An electrochemical impedance spectroscopy analysis confirms the charge transfer resistance.  X-ray photoelectron spectroscopy reveals stoichiometry at valance state of Cu2Se.

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References

Chen G, Seo J, Yang C, Prasad PN (2013) Nanochemistry and nanomaterials for photovoltaics. ChemSoc Rev 42:8304–38.

Khot K V., Mali SS, Pawar NB, et al (2014) Development of nanocoral-like Cd(SSe) thin films using an arrested precipitation technique and their application. New J Chem 38:5964–5974.

Page M, Niitsoo O, Itzhaik Y, et al (2009) Copper sulfide as a light absorber in wet-chemical synthesized extremely thin absorber (ETA) solar cells. Energy Environ Sci 2:220–223.

Jun HK, Careem MA, Arof AK (2014) Performances of some low-cost counter electrode materials in CdS and CdSe quantum dot-sensitized solar cells. Nanoscale Res Lett 9:69–76.

Liu F, Zhu J, Hu L, et al (2015) Low-temperature, solution-deposited metal chalcogenide films as highly efficient counter electrodes for sensitized solar cells. J Mater Chem A 3:6315–6323.

Dilena E, Dorfs D, George C, et al (2012) Colloidal Cu2−x(SySe1−y) alloy nanocrystals with controllable crystal phase: synthesis, plasmonic properties, cation exchange and electrochemical lithiation. J Mater Chem 22:13023–13031.

Li D, Zheng Z, Lei Y, et al (2010) Design and growth of dendritic Cu2−xSe and bunchy CuSe hierarchical crystalline aggregations. CrystEngComm 12:1856–1861.

Sagade AA, Sharma R (2008) Copper sulphide (CuxS) as an ammonia gas sensor working at room temperature. Sensors Actuators, B Chem 133:135–143.

Murali KR, Xavier RJ (2009) Characteristics of brush electroplated copper selenide thin films. Chalcogenide Lett 6:683–687.

Zhang P, Gao L (2003) Copper sulfide flakes and nanodisks. J Mater Chem 13:2007–2010.

Patil AR, Patil VN, Bhosale PN, Deshmukh LP (2000) Study of bismuth sulphoselenide thin films: Growth from the solution and properties. Mater Chem Phys 65:266–274.

Dhondge AD, Gosavi SR, Gosavi NM (2015) Influence of Thickness on the Photosensing Properties of Chemically Synthesized Copper Sulfide Thin Films. world J Condens matter Phys 5:1–9.

Jadhav SS, Mali SS, Hong CK, et al (2018) Arrested precipitation assembly of nanosheets Cu2ZnCd (S, Se)3 thin film for solar cell performance: Novel skilful synthesis. Mater Lett.

Jadhav SS, Hong CK, Patil PS, et al (2016) Novel synthesis of efficient counter electrode by facile arrested precipitation technique. J Mater Sci Mater Electron 4:3812–3820.

Zhang H, Penn RL, Lin Z, Cölfen H (2014) Nanocrystal growth via oriented attachment. CrystEngComm 16:1407–1408.

Patil SP, Mane RM, Kharade RR, Bhosale PN (2012) Novel synthetic route for quaternary MoBiGaSe 5 mixed metal chalcogenide (mmc ) thin films. Dig J Nanomater biostructures 7:237–245.

Ghanwat VB, Mali SS, Mane RM, et al (2015) Thermoelectric properties of nanocrystalline Cu3SSe4 thin films deposited by a self-organized arrested precipitation technique. New J Chem 39:5661–5668.

Mousavi-Kamazani M, Salavati-Niasari M, Sadeghinia M (2015) Facile hydrothermal synthesis, formation mechanism and solar cell application of CuInS2 nanoparticles using novel starting reagents. Mater Lett 142:145–149.

Pawar NB, Mali SS, Kharade SD, et al (2014) Influence of vacuum annealing on the structural and photoelectrochemical properties of nanocrystalline MoBi2S5 thin films. Curr Appl Phys 14:508–515.

Wang J, Xue D, Guo Y, et al (2011) Bandgap Engineering of Monodispersed Cu2-xSySe1-y Nanocrystals through Chalgen Ratio and Crystal Structure. J Am Chem Soc 18558–18561.

Nyandra, M., Suryasa, W. (2018). Holistic approach to help sexual dysfunction. Eurasian Journal of Analytical Chemistry, 13(3), pp. 207–212.

Muthoharoh, B. L., Kartini, F., & Fitriahadi, E. (2022). Pregnant women’s perceptions of anemia and iron supplement consumption. International Journal of Health & Medical Sciences, 5(2), 183-192. https://doi.org/10.21744/ijhms.v5n2.1902

Published

24-06-2022

How to Cite

Karape, S. M., Sirsat, D. M., Pakhare, K. S., Jadhav, S. S., & Sankpal, S. T. (2022). Synthesis and characterization of arrested precipitation assembled Cu2Se thin films. International Journal of Health Sciences, 6(S4), 6249–6258. https://doi.org/10.53730/ijhs.v6nS4.9605

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